Synthesis and Characterization of Binuclear Zn(II) Complex of N2O2S Symmetrical Potentially Pentadentate Schiff Base Ligand

Document Type: Research Paper

Authors

Department of Chemistry, Faculty of Science, Yazd University, 89195-741 Yazd, Iran

Abstract

The reactions of 1 - chloro - 2 - nitro benzene with 2 - Amino thio phenol yield the 2 - ( ( nitro phenyl ) thio ) aniline and then 2 , 2' - thio dianiline of this compound was prepared . Also the symmetrical potentially pentadentate N 2 O 2 S Schiff base ligand 2 , 2' - ( ( ( thio bis (1 , 2 - phenylene ) ) bis ( azanilidene ) ) bis ( methenilidene ) ) diphenol ( H 2 L ) obtain by added salicylaldehyde . These compound have been characterized by FT - IR , 1 H NMR and Mass Spectrometry . Bi - nuclear Zn ( II ) complex of this ligand was prepared and structurally characterized by X - ray crystallography . The coordination geometry around Zn ( II ) is intermediate between trigonal bipyramidal and square pyramidal , τ = 0.54.

Keywords

[1] A.A. Khandar, J. White, T. Taghvaee-Yazdeli, S.A.
Hosseini-Yazdi, P. McArdle, Inorg. Chim. Acta 400
(2013) 203.
[2] A. Bencini, V. Lippolis, Coord. Chem. Rev. 256 (2012)
149.
[3] P.A. Vigato, S. Tamburini, Coord. Chem. Rev. 248
(2004) 1717.
[4] N. Mangayarkarasi, M. Prabhakar, P.S. Zacharias,
Polyhedron 21 (2002) 925.
[5] S.R. Collinson, D.E. Fenton, Coord. Chem. Rev. 148
(1996) 19.
[6] I. Bertini, H.B. Gray, S.J. Lippard, J.S. Valentine, in:
Bioinorganic Chemistry, University Science Books,
Mill Valley, CA, USA, 1994.
[7] K.D. Karlin, Z. Tyeklar, A.D. Zuberbuhler, in: J. Reedjik (Ed.), Bioinorganic Catalysis, Marcel Dekker,
New York, 1993.
[8] K.D. Karlin, Z. Tyeklar, Adv. Inorg. Biochem. 9 (1993)
123.
[9] K.G. Strothkamp, S.J. Lippard, Acc. Chem. Res. 15
(1982) 318.
[10] W.N. Lipscomb, N. Straeter, Chem. Rev. 96 (1996)
2375.
[11] A. Looney, R. Han, K. McNeill, G. Parkin, J. Am.
Chem. Soc. 115 (1993) 4690.
[12] J.M. Guss, H.C. Freeman, J. Mol. Biol. 169 (1983) 521.
[13] E. Bouwman, J. Reedijk, Coord. Chem. Rev. 249
(2005) 1555.
[14] M. Taki, H. Hattori, T. Osako, S. Nagatomo, M. Shiro,
T. Kitagawa, S. Itoh, Inorg. Chim. Acta 357 (2004)
3369.
[15] G. Parkin, Chem. Rev. 104 (2004) 699.
[16] C. Liu, M. Wang, T. Zhang, H. Sun, Coord. Chem.
Rev. 248 (2004) 147.
[17] C. Dowling, G. Perkin, Polyhedron 15 (1996) 2463.
[18] P. Guerriero, S. Tamburini, P.A. Vigato, Coord. Chem.
Rev. 139 (1995) 17.
[19] E.E. Kim, H.W. Wyckoff, J. Mol. Biol. 218 (1991) 449.
[20] J.E. Coleman, Annu. Rev. Biophys. Biomol. Struct. 21
(1992) 441.
[21] S. Sarkar, K. Dey, Spectrochimica Acta Part A 62
(2005) 383.
[22] L.A. Saghatforoush, A. Aminkhani, F. Chalabian,
Trans. Met. Chem. 34 (2009) 899.
[23] A.A. Dehghani-Firouzabadi, H. Kargar, S. Eslaminejad,
B. Notash, J. Coord. Chem. 68 (2015) 4345.
[24] A.A. Dehghani-Firouzabadi, F. Motevaseliyan, Eur. J.
Chem. 5 (2014) 635.
[25] S.R. Guo, Y.Q. Yuam, Z. Kristallogr. New Cryst.
Struct. 223 (2008) 269.
[26] H. Keypour, R. Azadbakht, S. Salehzadeh, H.
Khanmohammadi, H. Khavasi, H. Adams, Polyhedron
27 (2008) 1631.
[27] B. Bosnich, J. Am. Chem. Soc. 90 (1968) 627.
[28] W.J. Geary, Coord. Chem. Rev. 1 (1972) 81.
[29] P.A. Vigato, S. Tamburini, D.E. Fenton, Coord. Chem.
Rev. 106 (1990) 25.
[30] A.W. Addison, T.N. Rao, J. Chem. Soc., Dalton Trans.
(1984) 1349.


Volume 2, Issue 1
Summer and Autumn 2018
Pages 115-122
  • Receive Date: 14 November 2016
  • Accept Date: 04 July 2016