TY - JOUR ID - 46376 TI - Synthesis and Characterization of Binuclear Zn(II) Complex of N2O2S Symmetrical Potentially Pentadentate Schiff Base Ligand JO - Inorganic Chemistry Research JA - J10.22036 LA - en SN - AU - Dehghani-Firouzabadi, Ahmad Ali AU - Alizadeh, Tahereh AD - Department of Chemistry, Faculty of Science, Yazd University, 89195-741 Yazd, Iran Y1 - 2018 PY - 2018 VL - 2 IS - 1 SP - 115 EP - 122 KW - Schiff base complex KW - Pentadentate ligand KW - Zn(II) complex KW - Binuclear complex KW - N2O2S donor DO - 10.22036/icr.2017.43519.1028 N2 - The reactions of 1 - chloro - 2 - nitro benzene with 2 - Amino thio phenol yield the 2 - ( ( nitro phenyl ) thio ) aniline and then 2 , 2' - thio dianiline of this compound was prepared . Also the symmetrical potentially pentadentate N 2 O 2 S Schiff base ligand 2 , 2' - ( ( ( thio bis (1 , 2 - phenylene ) ) bis ( azanilidene ) ) bis ( methenilidene ) ) diphenol ( H 2 L ) obtain by added salicylaldehyde . These compound have been characterized by FT - IR , 1 H NMR and Mass Spectrometry . Bi - nuclear Zn ( II ) complex of this ligand was prepared and structurally characterized by X - ray crystallography . The coordination geometry around Zn ( II ) is intermediate between trigonal bipyramidal and square pyramidal , τ = 0.54. UR - https://www.inorgchemres.org/article_46376.html L1 - https://www.inorgchemres.org/article_46376_670f577c7e9759d8b2d5448af7bd62d6.pdf ER -