%0 Journal Article %T Synthesis and Characterization of Binuclear Zn(II) Complex of N2O2S Symmetrical Potentially Pentadentate Schiff Base Ligand %J Inorganic Chemistry Research %I Iranian Chemical Society %Z 2538-1865 %A Dehghani-Firouzabadi, Ahmad Ali %A Alizadeh, Tahereh %D 2018 %\ 12/01/2018 %V 2 %N 1 %P 115-122 %! Synthesis and Characterization of Binuclear Zn(II) Complex of N2O2S Symmetrical Potentially Pentadentate Schiff Base Ligand %K Schiff base complex %K Pentadentate ligand %K Zn(II) complex %K Binuclear complex %K N2O2S donor %R 10.22036/icr.2017.43519.1028 %X The reactions of 1 - chloro - 2 - nitro benzene with 2 - Amino thio phenol yield the 2 - ( ( nitro phenyl ) thio ) aniline and then 2 , 2' - thio dianiline of this compound was prepared . Also the symmetrical potentially pentadentate N 2 O 2 S Schiff base ligand 2 , 2' - ( ( ( thio bis (1 , 2 - phenylene ) ) bis ( azanilidene ) ) bis ( methenilidene ) ) diphenol ( H 2 L ) obtain by added salicylaldehyde . These compound have been characterized by FT - IR , 1 H NMR and Mass Spectrometry . Bi - nuclear Zn ( II ) complex of this ligand was prepared and structurally characterized by X - ray crystallography . The coordination geometry around Zn ( II ) is intermediate between trigonal bipyramidal and square pyramidal , τ = 0.54. %U https://www.inorgchemres.org/article_46376_670f577c7e9759d8b2d5448af7bd62d6.pdf