Synthesis and characterization of metal complexes with new unsymmetrical Schiff base ligand derived from 2-aminoethanethiol

	Synthesis and characterization of metal complexes with new unsymmetrical Schiff base ligand derived from 2-aminoethanethiol
Articles in Press, Accepted Manuscript , Available Online from 26 December 2017
Document Type: Research Paper
DOI: 10.22036/icr.2017.94685.1039
Authors
Ahmad Ali Dehghani-Firouzabadi ; Seyed Hossein Mirmohammadi
Yazd University
Receive Date: 06 August 2017, Revise Date: 14 October 2017, Accept Date: 04 November 2017
Abstract
A new unsymmetric thioether diamine N - ( 2 - ( 2 - aminophenylthio) ethyl) benzene - 1 , 2 - diamine was prepared through the nucleophilic substitution of cysteaminium chloride with 1 - chloro - 2 - nitrobenzene and then the nitro groups of prepared compuond converted to the amine by zinc powder and ammonium chloride. Then, unsymmetric Schiff bass ligand 2 - ((( 2 - (( 2 - (( 2 - (( 2 - hydroxybenzylidene) amino)phenyl) amino) ethyl) thio) phenyl )imino) methyl )phenol [H2L] was synthesized via [2 + 1] condensation of 2-hydroxybenzaldehyde with this unsymmetric thioether diamine and the corresponding Schiff base complexes of this ligand were prepared by adding metal salts of Zn(II), Cu(II), Ni(II) and Mn(II). The thioether diamine, ligand and unsymmetric Schiff base complexes are characterized by FT - IR, UV - Vis, 1H NMR, 13C NMR spectroscopy, molar conductivity, microanalysis and mass spectrometry
Keywords
N3O2S donor; Unsymmetrical ligand; Schiff base ligand; Thioether ligand; 2-Aminoethanethiol


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