Plumbum(II) and Zinc(II) Complexes with 5-Chlorosalicylic Acid: Structure and Propertie

Document Type: Research Paper


Guangxi University for Nationalities


Abstract: Two new transition metal complexes, containing the acidic ligand 5-chlorosalicylic acid (H2L5), and 1,10-phenanthroline(phen) and 1,3-Di(4-pyridyl)propane (bpp) as secondary ligands are reported. They are formulated as {[Pb(HL5)2(phen)(H2O)]·H2O}n(1), [Zn2(HL5)4(bpp)2]n(2). All the complexes are characterized by single-crystal X-ray diffractions. Compoud 1 crystallizes in the triclinic P-1 space group while compoud 2 in the monoclinic system with space group C2/c. In compund 1, the carboxylate group of the coordinated HL5- adopt μ1−η1: η0 coordination fashion to connect one Pb(II) ion but all the carboxylate groups adopt the different μ1−η1: η1 mode in the crystal of compoud 2 compared to 1. In addition, the carboxylate group and Hydroxyl can partly or entirely deprotonated, which makes it possible to coordinating with metal ion or forming hydrogen bonding interactons. Furthermore, the fluorescence property in the solid state and thermal decomposition process were investigated in order to understand the relationships between the structures and the properties.


[1] a) M. Shibasaki, N. Yoshikawa, Chem. Rev. 102
(2002) 2187; b) E. Chelebaeva, J. Larionova, Y.
Guari, R.A. SaFerreira, L.D. Carlos, F.A.A. Paz, A.
Trifonov, C. Guerin, Inorg. Chem. 47 (2008) 775; c)
E. Chelebaeva, J. Larionova, Y. Guari, R.A.S.
Ferreira, L.D. Carlos, F.A.A. Paz, A. Trifonov, C.
Guerin, Inorg. Chem. 48 (2009) 5983; d) O. Guillou,
C. Daiguebonne, M. Camara, N. Kerbellec, Inorg.
Chem. 45 (2006) 8468.
[2] a) B. Zhao, X.Y. Chen, P. Cheng, D.Z. Liao, S.P.
Yan, Z.H. Jiang, J. Am. Chem. Soc. 126 (2004)
15394; b) B. Zhao, P. Cheng, Y. Dai, C. Cheng, D.Z.
Liao, S.P. Yan, Z.H. Jiang, G.L. Wang, Angew.
Chem., Int. Ed. 42 (2003) 934; c) H.-L. Gao, B. Zhao,
X.-Q. Zhao, Y. Song, P. Cheng, D.-Z. Liao, S.-P.
Yan, Inorg. Chem. 47 (2008) 11057; d) J.J. Zhang,
T.L. Sheng, S.M. Hu, S.Q. Xia, G. Leibeling, F.
Meyer, Z.Y. Fu, L. Chen, R.B. Fu, X.T. Wu, Chem.
Eur. J. 10 (2004) 3963.
[3] a) T.K. Ronson, T. Lazarides, H. Adams, S.J.A. Pope,
D. Sykes, S. Faulkner, S.J. Coles, M.D. Ward, Chem.
Eur. J. 12 (2006) 9299; b) C.-S. Lim, J. Jankolovits, P.
Zhao, J.W. Kampf, V.L. Pecoraro, Chem. -Asian J. 5
(2010) 46; c) J. Jankolovits, J.W. Kampf, S.
Maldonado, V.L. Pecoraro, Chem. Eur. J. 16 (2010)
[4] a) X.J. Kong, L.S. Long, Z.P. Zheng, R.B. Huang,
L.S. Zheng, Acc. Chem. Res. 43 (2010) 201; b) M.
Andruh, J.P. Costes, C. Diaz, S. Gao, Inorg. Chem. 48
(2009) 3342; c) C.E. Plečnik, S. Liu, S.G. Shore, Acc.
Chem. Res. 36 (2003) 499. Figure 12. View of the 3D
pillared-layer structure of III-A along the aaxis.
Figure 13. Solid-state emission spectra for I-D (a) and
II-B (b) at room temperature (excitation at 397 nm).
Crystal Growth & Design Article
cg300362d|Cryst. Growth Des. 12 (2012) 3549-3556.
[5] a) M.B. Zhang, J. Zhang, S.T. Zheng, G.Y. Yang,
Angew. Chem., Int. Ed. 44 (2005) 1385; b) J.W.
Cheng, J. Zhang, S.T. Zheng, G.Y. Yang, Angew.
Chem., Int. Ed. 45 (2006) 73.
[6] I.L. Karle, P. Venkateshwarlu, R. Nagaraj, A.V.S.
Sarma, D. Vijay, N.G. Sastry, S. Ranganathan, Chem.
Eur. J. 13 (2007) 4253.
[7] X. Xu, Y. Lu, E. Wang, Y. Ma, X. Bai, J. Mol. Struct.
(2006) 124.
[8] J. Min, J. Li, W. Chen, F.-X. Zhang, Struct. Chem. 17
(2006) 327.
[9] J. Rueff, S. Pillet, G. Bonaventure, M. Souhassou, P.
Rabu, Eur. J. Inorg. Chem. 23 (2003) 4173.
[10] Y. Wang, X. Zheng, W. Zhuang, L. Jin, Eur. J. Inorg.
Chem. 23 (2003) 1355.
[11] J.Y. Lu, V. Schauss, Inorg. Chem. Commun. 6 (2003)
[12] R. Wang, M. Hong, J. Luo, R. Cao, J. Weng, Chem.
Commun. 8 (2003) 1018.
[13] R. Wang, Y. Zhou, Y. Sun, D. Yuan, L. Han, B. Lou,
B. Wu, M. Hong, Cryst. Growth Des. 5 (2005) 251.
[14] R. Wang, M. Hong, J. Luo, R. Cao, J. Weng, Eur. J.
Inorg. Chem. 22 (2002) 2082.
[15] X. He, Y.-N. Li, G.-H. Li, Y.-Z. Li, P. Zhang, J.-N.
Xu, Y. Wang, Inorg. Chem. Commun. 8 (2005) 983.
[16] X.J. Wang, Y.H. Liu, C.Y. Xu, Q.Q. Guo, H.W. Hou,
Y.T. Fan, Cryst. Growth Des. 12 (2012) 2435.
[17] a) Q. Shi, Y. Sun, L. Sheng, K. Ma, M. Hu, X. Hu, S.
Huang, Cryst. Growth Des. 8 (2008) 3401; b) R. Cao,
Q. Shi, D. Sun, M. Hong, W. Bi, Y. Zhao, Inorg.
Chem. 41 (2002) 6161; c) X.X. Xu, Y. Lu, E.B.
Wang, Y. Ma, X.L. Bai, Cryst. Growth Des. 6 (2006)
2029; d) P. X.; Yin, Z. J.; Li, Y.Y. Qin, J.K. Cheng, L.
Zhang, Y.G. Yao, Chinese J. Struct. Chem. 27 (2008)
980; e) L.E. Kreno, K. Leong, O.K. Farha, M.
Allendorf, R.P. Van Duyne, J.T. Hupp, Chem. Rev.
112 (2012) 1105.
[18] X.M. Chen, G.F. Liu, Chem. Eur. J. 8 (2002) 4811.
[19] G.F. Liu, B.H. Ye, Y.H. Ling, X.M. Chen, Chem.
Commun. (2002) 1442.
[20] B.H. Ye, M.L. Tong, X.M. Chen, Coord. Chem. Rev.
249 (2005) 545.
[21] G.M. Sheldrick, SADABS, Program for Empirical
Absorption Correction of Area Detector; University of
G¨ottingen, Germany, 1996.
[22] G.M. Sheldrick, SHELXTL, Version 6.10, Software
Reference Manual; Bruker Instrumentation, Madison,
WI, 2000.

Volume 2, Issue 1
Summer and Autumn 2018
Pages 93-104
  • Receive Date: 06 April 2015
  • Revise Date: 21 June 2015
  • Accept Date: 13 May 2016