Inorganic Chemistry Research

Palladium Supported on Schiff Base Functionalized Magnetite Nanoparticles as an Efficient Catalyst for Coupling Reactions

Document Type : Research Paper

Authors

1 Hamedan University of Technology, 65155 Hamedan, Iran

2 Chemistry Department, Sharif University of Technology, P. O. Box: 11155-3615, Tehran, Iran

3 Faculty of Science, Department of Chemistry, Kosar University of Bojnord, Iran

4 Faculty of Chemistry, Bu-Ali Sina University, Hamedan 65174, Iran

Abstract

Palladium has been supported on 2-((3-(piperazin-1-yl) propylimino)methyl)phenol functionalized magnetite nanoparticles (denoted as Fe3O4@SiO2@L-Pd(II)). The supported Pd was used as an active heterogeneous catalyst in Suzuki cross-coupling reaction under solvent-free conditions. This nanocatalyst could be facilely separated via magnetic concentration and the isolated catalyst exhibited long-term stability. Easy work-up, high yield, recycling of the catalyst, low reaction times, non-toxicity of catalyst and and solvent-free conditions as an environmentally benign procedure are the main merits of this protocol.The produced catalyst were characterized by XRD, FT-IR, XPS, SEM, TEM, EDAX, VSM, TGA and ICP-OES.

Graphical Abstract

Palladium Supported on Schiff Base Functionalized Magnetite Nanoparticles as an Efficient Catalyst for Coupling Reactions

Keywords

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Inorganic Chemistry Research
Volume 5, Issue 1
Spring and Summer
2021
Pages 82-93
  • Receive Date: 05 September 2020
  • Revise Date: 31 December 2020
  • Accept Date: 03 January 2021
  • First Publish Date: 21 January 2021