An advanced graphene quantum dot/NiFe-layered double-hydroxide for water oxidation in a neutral solution

Document Type : Research Paper

Authors

1 Department of Chemistry, Faculty of Basic Sciences, Azarbaijan Shahid Madani University, P.O. BOX 53714-161, Tabriz, Iran

2 Department of Chemistry, Payame Noor University, P.O. BOX 19395-3697, Tehran, Iran

Abstract

Herein, it is reported that the nanocomposite of graphene quantum dot (GQD) and NiFe-layered double hydroxide (LDH) is a highly active and stable electrocatalyst for water oxidation. The GQD/NiFe-LDH composite was prepared using the hydrothermal method and investigated using X-ray diffraction (XRD) and Scanning electron microscopy (SEM). Based on the XRD and SEM results, the synthesis of GQD/NiFe-LDH was confirmed.  Then, the GQD/NiFe-LDH composite was applied as an effective electrocatalyst for water oxidation. The obtained results from linear sweep voltammetry (LSV) curves show that GQD/NiFe-LDH improved water oxidation reaction with the overpotential of 323 mV in neutral media in comparison with pure NiFe-LDH, GQD, and RuO2. The improved oxygen generation is due to the association of NiFe-LDH nano-plate with GQD. High activity of GQD/NiFe-LDH can be attributed to excellent electrical conductivity from GQD and high electrochemical activity due to the presence of NiFe-LDH. The stability of the electrocatalyst was investigated by water oxidation for 5.5 h.

Graphical Abstract

An advanced graphene quantum dot/NiFe-layered double-hydroxide for water oxidation in a neutral solution

Keywords


1. W. Zhang, W. Lai, R. Cao, Chem. Rev., 2017, 117,
3717-3797.
2. Z. Zhang, T. Zheng, X. Li, J. Xu, H. Zeng, Part. Part.
Syst. Charact., 2016, 33,457-472.
3. S. Wan, J. Qi, W. Zhang, W. Wang, S. Zhang, K. Liu,
H. Zheng, J. Sun, S. Wang, R. Cao, Adv. Mater., 2017,
29, 1700286.
4. A. M. M. I. Qureshy, M. Ahmed, I. Dincer, Int. J.
Hydrogen Energy, 2019, 44, 9237-9247.
5. S. Park, Y. Shao, J. Liu, Y. Wang, Energy Environ.
Sci., 2012, 5, 9331-9344.
6. H. Dau, C. Limberg, T. Reier, M. Risch, S. Roggan, P.
Strasser, Chem. Cat. Chem., 2010, 2, 724-761.
7. B. S. Yeo, A. T. Bell, J. Phys. Chem. C, 2012, 116,
8394-8400.
8. K. Liu, F. Wang, P. He, T. A. Shifa, Z. Wang, Z.
Cheng, X. Zhan, J. He, Adv. Energy Mater., 2018, 8,
1703290.
9. M. Liao, G. Zeng, T. Luo, Z. Jin, Y. Wang, X. Kou, D.
Xiao, Electrochim. Acta, 2016, 194, 59-66.
10. M.S. Burke, L.J. Enman, A.S. Batchellor, S. Zou,
S.W. Boettcher, Chem. Mater., 2015, 27, 7549-7558.
11. L. Zhang, Q. Fan, K. Li, S. Zhang, X. Ma, Sustainable
Energy Fuels, 2020, 4, 5417-5432.
12. F. Lu, M. Zhou, Y. Zhou, X. Zeng, Small, 2017, 13,
1701931.13. S. Sarabiyan Nejad, A. Babaie, M. Bagheri, M.
Rezaei, F. Abbasi, A. Shomali, Polym. Adv. Technol.,
2020, 31, 2279-2289.
14. Y. R. Kumar, K. Deshmukh, K. K. Sadasivuni, S. K.
K. Pasha, RSC Adv., 2020, 10, 23861-23898.
15. F. Gao, C. -L. Yang, G. Jiang, J. Photochem.
Photobiol. A, 2021, 407, 113080.
16. M. Wang, J. Fang, L. Hu, Y. Lai, Z. Liu, Int. J.
Hydrogen Energy, 2017, 42, 21305-21310.
17. M. C. Daugherty, S. Gu, D. S. Aaron, R. E. Kelly, Y.
Ashraf Gandomi, C. -T. Hsieh, Nanoscale, 2020, 12,
7834-7842.
18. N. Dewangan, W. M. Hui, S. Jayaprakash, A. -R.
Bawah, A. J. Poerjoto, T. Jie, A. Jangam, K. Hidajat, S.
Kawi, Catal. Today, 2020, 356, 490-513.
19. M. M. J. Li, C. Chen, T. Ayvalı, H. Suo, J. Zheng, I.
F. Teixeira, L. Ye, H. Zou, D. O’Hare, S. C. E. Tsang,
ACS Catal., 2018, 8, 4390-4401.
20. J. J. Gil, O. Aguilar-Martínez, Y. Piña-Pérez, R.
Pérez-Hernández, C. E. Santolalla-Vargas, R. Gómez,
F. Tzompantzi, Renewable Energy, 2020, 145, 124-132.
21. H. S. Jadhav, A. Roy, B. Z. Desalegan, J. G. Seo,
Sustainable Energy Fuels, 2020, 4, 312-323.
22. B. Ma, A. Fernandez-Martinez, S. Grangeon, C.
Tournassat, N. Findling, S. Carrero, D. Tisserand, S.
Bureau, E. Elkaïm, C. Marini, G. Aquilanti, A. Koishi,
N. C. M. Marty, L. Charlet, Environ. Sci. Technol.,
2018, 52, 1624-1632.
23. S. Mallakpour, M. Hatami, Polym., 2018, 154, 188-
199.
24. H. Yuan, Y. Wang, C. Yang, Z. Liang, M. Chen, W.
Zhang, H. Zheng, R. Cao, Chem. Phys. Chem., 2019,
20, 2964-2967.
25. Y. -C. Chen, W. -H. Chiang, D. Kurniawan, P. -C.
Yeh, K. -I. Otake, C. -W. Kung, ACS Appl. Mater.
Interfaces, 2019, 11, 35319-35326.
26. A. Naddaf, S. Zeinali Heris, Int. Commun. Heat Mass
Transfer, 2018, 95,116-122.
27. J. Peng, W. Gao, B. K. Gupta, Z. Liu, R. RomeroAburto, L. Ge, L. Song, L. B. Alemany, X. Zhan, G.
Gao, Nano Lett., 2012, 12, 844-849.
28. C. Pang, S. Han, Y. Li, J. Zhang, J. Chin. Chem. Soc.,
2018, 65, 1504-1509.
29. Y. Gao, Z. Zhao, H. Jia, X. Yang, X. Lei, X. Kong, F.
Zhang, J. Mater. Sci., 2019, 54, 14515-14523.
30. S. Sanati, Z. Rezvani, Ultrason. Sonochem., 2018, 48,
199-206.
31. C. Nethravathi, T. Nisha, N. Ravishankar, C.
Shivakumara, M. Rajamathi, Carbon, 2009, 47, 2054-
2059.
32. D. Tang, J. Liu, X. Wu, R. Liu, X. Han, Y. Han, H.
Huang, Y. Liu, Z. Kang, ACS Appl. Mater. Interfaces,
2014, 6, 7918-7925.
33. D. Pan, S. Ge, J. Zhao, Q. Shao, L. Guo, X. Zhang, J.
Lin, G. Xu, Z. Guo, Dalton Trans., 2018, 47, 9765-
9778.
34. S. Ramachandran, M. Sathishkumar, N. K. Kothurkar,
R. Senthilkumar, Mater. Sci. Eng., 2018, 310, 012139.
35. Z. -C. Yang, M. Wang, A. M. Yong, S. Y. Wong, XH. Zhang, H. Tan, A. Y. Chang, X. Li, J. Wang, Chem.
Commun., 2011, 47, 11615-11617.
36. D. Arthisree, G. M. Joshi, J. Mater. Sci., 2017, 28,
10516-10524.
37. J. P. Naik, P. Sutradhar, M. Saha, J. Nanostruct.
Chem., 2017, 7, 85-89.
38. S. Tonda, S. Kumar, M. Bhardwaj, P. Yadav, S.
Ogale, ACS Appl. Mater. Interfaces, 2018, 10, 2667-
2678.
39. L. -J. Zhou, X. Huang, H. Chen, P. Jin, G. -D. Li, X.
Zou, Dalton Trans., 2015, 44, 11592-11600.
40. J. Bao, Z. Wang, J. Xie, L. Xu, F. Lei, M. Guan, Y.
Huang, Y. Zhao, J. Xia, H. Li, Inorg. Chem. Front.,
2018, 5, 2964-2970.
41. L. Jafari Foruzin, Z. Rezvani, B. Habibi, Appl. Clay
Sci., 2020, 188, 105511.
42. L. Jafari Foruzin, B. Habibi, Z. Rezvani, New J.
Chem., 2018, 42, 13963-13970.
43. D. -C. Xia, L. Zhou, S. Qiao, Y. Zhang, D. Tang, J.
Liu, H. Huang, Y. Liu, Z. Kang, Mater. Res. Bull.,
2016, 74, 441-446.
44. X. Long, J. Li, S. Xiao, K. Yan, Z. Wang, H. Chen, S.
Yang, Angew. Chem., 2014, 126, 7714-7718.