Inorganic Chemistry Research
Synthesis and characterization of a dioxomolybdenum(VI) aminohydrazone complex and its performance as an efficient homogeneous catalyst in the selective oxidation of benzylic alcohols
Document Type : Research Paper
Authors
1 Department of Chemical Engineering, Faculty of Engineering, Ardakan University, P.O. Box 184, Ardakan, Iran
2 Department of Chemistry, Payame Noor University, 19395-3697, Tehran, Iran
Abstract
A dioxomolybdenum(VI) complex was successfully synthesized by the reaction between [MoO2(acac)2] and a tridentate ligand obtained from the condensation of 4-aminobenzohydrazide and 3-ethoxysalicylaldehyde. The structures of synthesized products were explored through elemental analysis (CHN) and various spectroscopic techniques such as FT-IR, 1H NMR, and 13C NMR. Moreover, the complex was utilized in the selective oxidizing of benzylic alcohols to the corresponding aryl aldehydes by the use of urea hydrogen peroxide (UHP) in acetonitrile under reflux conditions. The present protocol has several advantages, including short reaction times, high product yields, and simplicity in operation.
Graphical Abstract
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Keywords
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Volume 5, Issue 2
Autumn and Winter 2021Pages 201-206
- Receive Date: 05 June 2021
- Revise Date: 22 July 2021
- Accept Date: 23 July 2021
- First Publish Date: 14 August 2021