Voltammetric and Amperometric Determination of Iodate using Ionic Liquid/Polyoxotungstate/MWCNTs-COOH Organic-Inorganic Nanohybrid Modified Glassy Carbon Electrode

Document Type : Research Paper

Authors

Department of Chemistry, Faculty of Sciences, University of Hormozgan, Bandar Abbas 79161-93145, Iran

Abstract

In this study, a nanohybrid modified glassy carbon electrode (GCE) was successfully fabricated with a tri-component nanocomposite consisting of (1,1'-(1,4-Butanediyl) dipyridinium) ionic liquid (bdpy), PW11O39Co(H2O) (PW11Co) polyoxometalate (POM), and carboxyl functionalized multi-walled Carbon Nanotubes (MWCNTs-COOH) by drop-casting, followed by electrodeposition technique. The morphological, electrochemical, and electrocatalytic properties of the (bdpy)PW11Co/MWCNTs-COOH/GCE were investigated by field emission scanning electron microscopy (FE-SEM) combined with energy-dispersive X-ray spectroscopy, voltammetry, and amperometry methods. The FE-SEM images well showed immobilization of (bdpy)PW11Co/MWCNTs-COOH on GCE through deformation of the mirror surface to the rough surface. The electrochemical test results confirmed that modified electrode has high stability and remarkable electrocatalytic behavior toward the reduction of iodate ion. The proposed sensor displayed two linear ranges of 10.0-200.0, and 200.0-1600.0 µmol L-1 with LOD of 27.6×10-2 µmol L-1 (S/N=3), and sensitivity of 41.0 µA mmol L-1, and 20.0 µA mmol L-1, respectively, by amperometry method. Moreover, the results of the electrochemical experiments indicated that this sensor has excellent selectivity, good reproducibility, repeatability, and analytical performance in real samples.

Graphical Abstract

Voltammetric and Amperometric Determination of Iodate using Ionic Liquid/Polyoxotungstate/MWCNTs-COOH Organic-Inorganic Nanohybrid Modified Glassy Carbon Electrode

Keywords


1. L. Wang, T. Meng, J. Sun, S. Wu, M. Zhang, H. Wang,
Y. Zhang, Anal. Chim. Acta, 2019, 1047, 28-35.
2. Y. Tanaka, T. Hasegawa, T. Shimamura, H. Ukeda, T.
Ueda, J. Electroanal. Chem. 2018, 828, 102-107.
3. M. Chi, Z. Zhu, L. Sun, T. Su, W. Liao, C. Deng, Y.
Zhao, W. Ren, H. Lü, Appl. Catal. B, 2019, 259,
118089-118098.
4. Y. Jia, S. Sun, X. Cui, X. Wang, L. Yang, Talanta
2019, 205, 120139-120144.
5. Q. Huang, S. Ke, L. Qiu, X. Zhang, S. Lin, Chem. Cat.
Chem., 2014, 6, 1531-1534.
6. M. Jiang, D. Zhu, J. Cai, H. Zhang, X. Zhao, J. Phys.
Chem. C, 2014, 118, 14371-14378.
7. S. Dianat, A. Bordbar, S. Tangestaninejad, S. ZarkeshEsfahani, P. Habibi, A. A. Kajani, J. Iran. Chem.
Soc., 2016, 13, 1895-1904.
8. S. Dianat, A. -K. Bordbar, S. Tangestaninejad, B.
Yadollahi, R. Amiri, S. -H. Zarkesh-Esfahani, P.
Habibi, J. Inorg. Biochem., 2015, 152, 74-81.
9. J. T. Rhule, C. L. Hill, D. A. Judd, R. F. Schinazi,
Chem. Rev., 1998, 98, 327-358.
10. S. Omwoma, C. T. Gore, Y. Ji, C. Hu, Y. -F. Song,
Coord. Chem. Rev., 2015, 286, 17-29.
11. D. -Y. Du, J. -S. Qin, S. -L. Li, Z. -M. Su, Y. -Q. Lan,
Chem. Soc. Rev., 2014, 43, 4615-4632.
12. Q. Wang, J. Khungwa, L. Li, Y. Liu, X. Wang, S.
Wang, J. Electroanal. Chem., 2018, 824, 91-98.
13. F. Boussema, R. Haddad, Y. Ghandour, M. S.
Belkhiria, M. Holzinger, A. Maaref, S. Cosnier,
Electrochim. Acta, 2016, 222, 402-408.
14. A. Proust, B. Matt, R. Villanneau, G. Guillemot, P.
Gouzerh, G. Izzet, Chem. Soc. Rev., 2012, 41, 7605-
7622.
15. S. Dianat, A. Hatefi-Mehrjardi, K. Mahmoodzadeh, S.
Kakhki, New J. Chem., 2019, 43, 14417-14425.16. M. Ammam, J. Mater. Chem. A, 2013, 1, 6291-6312.
17. Y. Z. Liu, W. Yao, H. M. Gan, C. Y. Sun, Z. M. Su,
X. L. Wang, Chem. Eur. J., 2019, 25, 16617-16624.
18. D. Martel, N. Sojic, A. Kuhn, J. Chem. Educ., 2002,
79, 349-352.
19. L. Adamczyk, J. Solid State Electrochem., 2017, 21,
211-222.
20. R. Ayranci, Y. Torlak, T. Soganci, M. Ak, J.
Electrochem. Soc., 2018, 165, B638-B643.
21. L. Ni, G. Yang, C. Sun, G. Niu, Z. Wu, C. Chen, X.
Gong, C. Zhou, G. Zhao, J. Gu, W. Ji, X. Huo, M.
Chen, G. Diao, Mater. Today Energy, 2017, 6, 53-64.
22. H. Yang, T. Song, L. Liu, A. Devadoss, F. Xia, H.
Han, H. Park, W. Sigmund, K. Kwon, U. Paik, J.
Phys. Chem. C, 2013, 117, 17376-17381.
23. L. -H. Gao, J. -F. Zhang, H. -L. Wang, X. -Y. Lin, J.
-M. Qi, K. -Z. Wang, Electrochim. Acta, 2015, 166,
215-222.
24. H. Li, S. Pang, S. Wu, X. Feng, K. Müllen, C.
Bubeck, J. Am. Chem. Soc., 2011, 133, 9423-9429.
25. J. Ni, Q. -M. Fu, L. Liu, Z. -R. Gu, Z. Zhou, F. -B. Li,
S. -X. Zhang, S. -Z. Liu, Z. -L. Du, Thin Solid Films,
2013, 537, 247-251.
26. C. P. Ponce, H. Y. Araghi, N. K. Joshi, R. P. Steer, M.
F. Paige, Langmuir, 2015, 31, 13590-13599.
27. S. Dianat, A. Hatefi-Mehrjardi, K. Mahmoodzadeh,
New J. Chem., 2019, 43, 1388-1397.
28. M. Blasco-Ahicart, J. Soriano-López, J. J. Carbó, J.
M. Poblet, J. -R. Galan-Mascaros, Nat. Chem., 2018,
10, 24-30.
29. B. Suma, P. S. Adarakatti, S. K.
Kempahanumakkagari, P. Malingappa, Mater. Chem.
Phys., 2019, 229, 269-278.
30. W. Guo, X. Cao, Y. Liu, X. Tong, X. Qu, J.
Electrochem. Soc., 2014, 161, B248-B255.
31. J. M. Cameron, D. J. Wales, G. N. Newton, Dalton
Trans., 2018, 47, 5120-5136.
32. F. -Y. Yi, W. Zhu, S. Dang, J. -P. Li, D. Wu, Y. -H.
Li, Z. -M. Sun, Chem. Commun., 2015, 51, 3336-
3339.
33. D. -C. Zhao, Y. -Y. Hu, H. Ding, H. -Y. Guo, X. -B.
Cui, X. Zhang, Q. -S. Huo, J. -Q. Xu, Dalton Trans.,
2015, 44, 8971-8983.
34. E. Rafiee, F. Mirnezami, J. Mol. Liq., 2014, 199, 156-
161.
35. R. Wang, D. Jia, Y. Cao, Electrochim. Acta, 2012, 72,
101-107.
36. X. Wu, W. Wu, Q. Wu, W. Yan, Langmuir, 2017, 33,
4242-4249.
37. F. Faridbod, H. Rashedi, M. R. Ganjali, P. Norouzi, S.
Riahi, Application of room temperature ionic liquids
in electrochemical sensors and biosensors, Intech
Open Access Publisher, 2011.
38. G. Bajwa, M. Genovese, K. Lian, ECS J. Solid State
Sci. Technol., 2013, 2, M3046-M3050.
39. A. A. Ensafi, E. Heydari-Soureshjani, M. Jafari-Asl,
B. Rezaei, Carbon, 2016, 99, 398-406.
40. D. M. Fernandes, M. P. Araújo, A. Haider, A. S.
Mougharbel, A. J. Fernandes, U. Kortz, C. Freire,
Chem. Electro. Chem., 2018, 5, 273-283.
41. L. Hong, Y. Gui, J. Lu, J. Hu, J. Yuan, L. Niu, Int. J.
Hydrogen Energy, 2013, 38, 11074-11079.
42. J. Jiao, J. Zuo, H. Pang, L. Tan, T. Chen, H. Ma, J.
Electroanal. Chem., 2018, 827, 103-111.
43. N. Thakur, S. Das Adhikary, M. Kumar, D. Mehta, A.
K. Padhan, D. Mandal, T. C. Nagaiah, ACS Omega,
2018, 3, 2966-2973.
44. C. Deng, J. Chen, Z. Nie, M. Yang, S. Si, Thin Solid
Films, 2012, 520, 7026-7029.
45. S. Yang, X. Liu, X. Zeng, B. Xia, J. Gu, S. Luo, N.
Mai, W. Wei, Sens. Actuators B, 2010, 145, 762-768.
46. D. Zhang, H. Ma, Y. Chen, H. Pang, Y. Yu, Anal.
Chim. Acta, 2013, 792, 35-44.
47. J. Hu, Y. Ji, W. Chen, C. Streb, Y. -F. Song, Energy
Environ. Sci., 2016, 9, 1095-1101.
48. G. Y. Lee, I. Kim, J. Lim, M. Y. Yang, D. S. Choi, Y.
Gu, Y. Oh, S. H. Kang, Y. S. Nam, S. O. Kim, J.
Mater. Chem. A, 2017, 5, 1941-1947.
49. S. Liu, L. Xu, F. Li, W. Guo, Y. Xing, Z. Sun,
Electrochim. Acta, 2011, 56, 8156-8162.
50. S. Iijima, Nature, 1991, 354, 56-58.
51. B. Ertan, T. Eren, İ. Ermiş, H. Saral, N. Atar, M. L.
Yola, J. Colloid Interface Sci., 2016, 470, 14-21.
52. X. Kong, Y. Wang, Q. Zhang, T. Zhang, Q. Teng, L.
Wang, H. Wang, Y. Zhang, J. Colloid Interface Sci.,
2017, 505, 615-621.
53. S. Li, X. Yu, G. Zhang, Y. Ma, J. Yao, B. Keita, N.
Louis, H. Zhao, J. Mater. Chem., 2011, 21, 2282-
2287.
54. A. Manivel, R. Sivakumar, S. Anandan, M.
Ashokkumar, Electrocatalysis, 2012, 3, 22-29.
55. S. Zhang, P. He, W. Lei, G. Zhang, J. Electroanal.
Chem., 2014, 724, 29-35.
56. J. Zuo, N. Gao, Z. Yu, L. Kang, K. P. O’Halloran, H.
Pang, Z. Zhang, H. Ma, J. Electroanal. Chem., 2015,
751, 111-118.
57. M. Sharifi, S. Dianat, A. Hosseinian, RSC Adv., 2021,
11, 8993-9007.
58. A. Karimi-Takallo, S. Dianat, A. Hatefi-Mehrjardi, J.
Electroanal. Chem., 2021, 886, 115139-115151.
59. W. Song, X. Chen, Y. Jiang, Y. Liu, C. Sun, X. Wang,
Anal. Chim. Acta, 1999, 394, 73-80.
60. Y. Li, W. Bu, L. Wu, C. Sun, Sens. Actuators B, 2005,
107, 921-928.
61. A. Salimi, H. MamKhezri, R. Hallaj, S. Zandi,
Electrochim. Acta, 2007, 52, 6097-6105.
62. M. Zhou, L. -P. Guo, F. -Y. Lin, H. -X. Liu, Anal.
Chim. Acta, 2007, 587, 124-131.
63. B. Haghighi, H. Hamidi, Electroanalysis, 2009, 21,
1057-1065.64. B. Haghighi, H. Hamidi, L. Gorton, Electrochim.
Acta, 2010, 55, 4750-4757.
65. M. Nosuhi, A. Nezamzadeh-Ejhieh, J. Electroanal.
Chem., 2018, 810, 119-128.
66. J. Pishahang, H. B. Amiri, H. Heli, Sens. Actuators B,
2018, 256, 878-887.
67. F. Koohi, H. R. Zare, Z. Shekari, Microchem. J.,
2020, 159, 105425-105433.
68. M. Vithanage, I. Herath, S. Achinthya, T. Bandara, L.
Weerasundara, S. Mayakaduwa, Y. Jayawardhana, P.
Kumarathilaka, Arch. Public Health, 2016, 74, 21-27.
69. L. Berța, F. Boda, G. S. A, A. Curticapean, D.
Muntean, Acta Med. Marisiensis, 2014, 60, 84-88.
70. P. -E. Car, B. Spingler, S. Weyeneth, J. Patscheider,
G. R. Patzke, Polyhedron, 2013, 52, 151-158.
71. M. Kato, C. N. Kato, Inorg. Chem. Commun., 2011,
14, 982-985.
72. A. P. Lever, Stud. Phys. Theor. Chem., 1984, 33, 99-
100.
73. A. J. Haider, M. Mohammed, D. S. Ahmed, Int. J.
Eng. Res., 2014, 5, 255-261.
74. P. Nie, C. Min, H. -J. Song, X. Chen, Z. Zhang, K.
Zhao, Tribol. Lett., 2015, 58, 7-18.
75. H. Ohno, Electrochemical aspects of ionic liquids,
John Wiley & Sons, 2005.
76. Z. Liu, M. Jin, J. Cao, J. Wang, X. Wang, G. Zhou, A.
van den Berg, L. Shui, Sens. Actuators B, 2018, 257,
1065-1075.
77. D. Zhu, H. Ma, Q. Zhen, J. Xin, L. Tan, C. Zhang, X.
Wang, B. Xiao, Appl. Surf. Sci., 2020, 526, 146721-
146732.