Two-dimensional Manganese(II) Coordination Polymer Complex Containing Aqua, Diethyl Phosphate and Chloride Ligands: Synthesis, Spectroscopic Characterization, Thermal Analyses, and Crystal Structure

Document Type : Research Paper

Authors

1 Department of Chemistry, Farhangian University, Tehran, Iran

2 Faculty of Chemistry, Kharazmi University, Tehran, Iran

Abstract

A new two-dimensional manganese(II) coordination polymer, [Mn(μ-DEP)(μ-Cl)(H2O)2]n (1) (DEP is diethyl phosphate), was prepared from the reaction of MnCl2.4H2O and TEP (TEP is triethyl phosphate) ligand in mixture of H2O/CH3OH (1:10) at 40 °C. Suitable crystals of this complex for crystal structure determination were obtained by slow evaporation of the produced colorless solution at room temperature. Complex 1 was characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The X-ray structural analysis indicated that the manganese(II) is six-coordinated in a distorted octahedral configuration by four oxygen atoms from two water and two bridged diethyl phosphate ligands and two bridged chloride anions. Also, the thermal stability of 1 was studied by thermogravimetric and differential thermal analyses.

Keywords

References

[1]  G.Zhang, H. Zeng, S. Li, J. Johnson, Z. Mo, M.C. Neary, S. Zheng, Dalton Trans.        49 (2020) 2610.
[2] H. Huang, W. Gao, F. Liu, X. M. Zhang, J. P. Liu. Inorg. Chim. Acta 484 (2019)        414.
[3] J. Chen, M. Chen, B. Zhang, R. Nie, A. Huang, T. W. Goh, A. Volkov, Z. Zhang,       Q. Rena, W. Huang, Green Chem. 21 (2019) 3629.
[4] Y. Peng, H. Huang1, Y. Zhang, C. Kang, S. Chen, L. Song, D. Liu, C. Zhong,             Nature  Comm. 9 (2018)187.
[5] E. R. Engel, J. L. Scott, Green Chem. 22 (2020) 3693.
[6] S. E. Miller, M. H. Teplensky, P. Z. Moghadam,  D. F. Jimenez, Interface Focus, 6      (2016) 20160027.
[7] P. A. Dhas, N. Deshmukh, P. Caro, C. Patil, P. Luisa García-Martín, M. Padya, B.        Nikam, A. Mehta, T.  Mutalik,  Coord. Chem. Rev. 409 (2020) 213212.
[8] H. Bunzen, M. Grzywa, R. Aljohani, H. A. K. Nidda, D. Volkmer. Eur. J. Inorg.          Chem. (2019) 4471.
[9] T. Gong, X. Yang, Q. Sui, Y. Qi, F. G. Xi,  E. Q. Gao, Inorg. Chem. 55 (2016) 96.
[10] Z. B. Han, R. Y. Lu, Y. F. Liang, Y. L. Zhou, Q. Chen, M. H. Zeng, Inorg.                   Chem. 51 (2012) 674.
[11] H. Furukawa, K. E. Cordova, M. O’Keeffe, O. M. Yaghi, Science, 341 (2013)             947.
[12] W. Q. Kan, Y. C. He, Z. C. Zhang, Y. H. Kan, S. Z. Wen. J. Iran. Chem. Soc. 16          (2019) 2021.
[13] F. Yuan, H. S. Yu, C. M. Yuan, C. S. Zhou, F. Li, Y. J. Lu, X. Y. Ling, J. Wang,          A. Singh, A. Kumar. Inorg. Chim. Acta, 449 (2020) 119189.
[14] Q. Q. Xiao, D. Liu, Y. L. Wei, G. H. Cui, J. Solid State Chem. 273 (2019) 67.
[15] W. P. Lustig, S. Mukherjee, N. D. Rudd, A. V. Desai, J. Li,  S. K. Ghosh, Chem.         Soc. Rev. 46 (2017) 3242.
[16] H. H. Willard, H. Freund. Ind. Eng. Chem. 18 (1946) 195.
[17] B. S. Fales, N. O. Fujamade, Y. w. Nei, J. Oomens, M. T. Rodgers, J. Am. Soc.          Mass Spectrom. 22 (2011) 81.
[18] J. Stangret, R. Savoie, Canad. J. Chem. 70 (1992) 2875.
[19] P. Mäkie, P. Persson, L. Österlund, Journal of Colloid and Interface Science, 392        (2013) 349.
[20] A. D. Sutton, I. May, C. A. Sharrad, M. J. Sarsfield, M. Helliwell, Dalton Trans.         (2006) 5734.
[21] R. Kanellakopulos, E. Dornberger, R. Maier, Z. Anorg. Allg. Chem. 619 (1993)          593.
[22] G. H. John, I. May, C. A. Sharrad, A. D. Sutton, D. Collison, M. Helliwell, M.J.         Sarsfield, Inorg. Chem. 44 (2005) 7606.
[23] Y. Kyogoku, Y. Iitaka, Acta Crystalloger. 21 (1966) 49.
[23] M. Rafizadeh, V. Amani,  Anal. Sci. 22 (2006) x211.
[44] V. Amani, M. Rafizadeh, M. Yousefi, N. S. Zargar, Anal. Sci. 22 (2006) x303.
[25] M. Rafizadeh, V. Amani, N. S. Mortazavi, Bull. Korean Chem. Soc. 30 (2009)           489.
[26] G.M. Sheldrick. SADABS. Madison, WI, USA: Bruker AXS, 1998.
[27] Bruker SMART and SAINT. Madison, WI, USA: Bruker AXS Inc. 1998.
[28] G.M. Sheldrick. Acta Crystallogr., A64 (2008) 112.
[29] L.J. Farrugia, J. Appl. Crystallogr. 32 (1999) 837.
[30] L.J. Farrugia, J. Appl. Crystallogr. 30 (1997) 565.
[31] A. L.Spek, Acta Crystallogr. E76 (2020) 1.
[32] Mercury 141. Copyright Cambridge Crystallographic Data Center. Cambridge,           (2001-2005).
[33] M. Rafizadeh, R. Tayebee, V. Amani, M. Nasseh, Cryst. Bull. Korean Chem.              Soc. 26 (2005) 594.
[34]  M. Rafizadeh, V. Amani, H. Farajian, Z. Anorg. Allg. Chem. 633 (2007) 1143.
[35]  M. Rafizadeh, V. Amani,  Z. Anorg. Allg. Chem. 633 (2007) 2738.
[36] M. Rafizadeh, R. Tayebee, V. Amani, Turk. J. Chem. 29 (2005) 385.
[37] H. A. Chu, W. Hillier, N. A. Law, G. T. Babcock, Biochim. Biophys. Acta,
       1503 (2001) 69.
[38] V. Amani, N. Faal Hamedani, Mol. Cryst. Liq. Cryst. 665 (2018) 207.
[39] N. K. Jha, B. N. Thakur,  Synt. & React. Inorg. Met. Org. Chem. 14 (1984) 1057.
[40] D. A. Thornton, G. M. Watkins, J. Coord. Chem. 25 (1992) 299.
[41] M. B. Zhang, Y. M. Chen, S. T. Zheng, G. Y.Yang, Eur. J. Inorg. Chem. (2006)         1423.
[42] M. Rafizadeh, V. Amani, H. Aghayan, Acta Crystalloger. E62 (2006) m2450.
[43] G. X. Wang, J. Yin, J. Li, Z. B. Yin, W. X. Zhang,  Z. Xi, Inorg. Chem. Front. 6         (2019) 428.
[44] T.B. Richardson, S. deGala, R.H. Crabtree, P.E.M. Siegbahn, J. Am. Chem. Soc.
       117 (1995) 12875.
[45] A. S. Batsanov, Acta Crystalloger. E74 (2018) 570.
[46] C. F. Matta, J. H. Trujillo,T. H. Tang, R. F. W. Bader,Chem. Eur. J. 9 (2003) 1940.
Inorganic Chemistry Research
Volume 4, Issue 1
Spring and Summer
2020
Pages 20-27

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History

  • Receive Date: 19 June 2020
  • Revise Date: 24 June 2020
  • Accept Date: 25 June 2020

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